全文获取类型
收费全文 | 36513篇 |
免费 | 4134篇 |
国内免费 | 6378篇 |
专业分类
化学 | 28332篇 |
晶体学 | 1272篇 |
力学 | 753篇 |
综合类 | 367篇 |
数学 | 7018篇 |
物理学 | 9283篇 |
出版年
2024年 | 35篇 |
2023年 | 439篇 |
2022年 | 657篇 |
2021年 | 917篇 |
2020年 | 1302篇 |
2019年 | 1313篇 |
2018年 | 1118篇 |
2017年 | 1445篇 |
2016年 | 1399篇 |
2015年 | 1245篇 |
2014年 | 1707篇 |
2013年 | 3238篇 |
2012年 | 2106篇 |
2011年 | 2650篇 |
2010年 | 2264篇 |
2009年 | 2676篇 |
2008年 | 2673篇 |
2007年 | 2542篇 |
2006年 | 2434篇 |
2005年 | 2199篇 |
2004年 | 1957篇 |
2003年 | 1590篇 |
2002年 | 1327篇 |
2001年 | 1127篇 |
2000年 | 964篇 |
1999年 | 780篇 |
1998年 | 669篇 |
1997年 | 587篇 |
1996年 | 514篇 |
1995年 | 572篇 |
1994年 | 505篇 |
1993年 | 422篇 |
1992年 | 330篇 |
1991年 | 233篇 |
1990年 | 150篇 |
1989年 | 150篇 |
1988年 | 133篇 |
1987年 | 81篇 |
1986年 | 79篇 |
1985年 | 79篇 |
1984年 | 64篇 |
1983年 | 36篇 |
1982年 | 53篇 |
1981年 | 49篇 |
1980年 | 52篇 |
1979年 | 43篇 |
1978年 | 32篇 |
1977年 | 29篇 |
1976年 | 15篇 |
1975年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
11.
《Mendeleev Communications》2022,32(1):105-108
A mixed-metal 1D coordination polymer [CaCu(HBTC)2(H2O)8]n (where H3BTC – benzene-1,3,5-tric arboxylic acid) was obtained in a solvothermal synthesis of a well-known copper-containing metal–organic framework [Cu3(BTC)2(H2O)3]n (HKUST-1) in autoclaves 3D-printed from commercial polypropylene. This material was a source of calcium ions, apparently, leaking from a colorant (calcium carbonate) promoted by glacial acetic acid as a modulator used to produce large single crystals of HKUST-1. This finding was confirmed by elemental analysis and a model experiment that resulted in a new calcium-based 1D coordination polymer [Ca(H2BTC)2(H2O)5]n under the same solvothermal conditions with no copper or calcium salts put into a 3D-printed autoclave. 相似文献
12.
Given a graph sequence denote by T3(Gn) the number of monochromatic triangles in a uniformly random coloring of the vertices of Gn with colors. In this paper we prove a central limit theorem (CLT) for T3(Gn) with explicit error rates, using a quantitative version of the martingale CLT. We then relate this error term to the well-known fourth-moment phenomenon, which, interestingly, holds only when the number of colors satisfies . We also show that the convergence of the fourth moment is necessary to obtain a Gaussian limit for any , which, together with the above result, implies that the fourth-moment condition characterizes the limiting normal distribution of T3(Gn), whenever . Finally, to illustrate the promise of our approach, we include an alternative proof of the CLT for the number of monochromatic edges, which provides quantitative rates for the results obtained in [7]. 相似文献
13.
Herein, we successfully construct the 3D biocompatible graphene through crosslinking 2D graphene nanosheet onto carbon fiber paper with poly(diallyldimethylammonium chloride) (PDDA) as anode of the alcohol biofuel cell. Compared with the bioanode without 3D graphene, the current density and output power of PDDA-graphene-ADH bioanode is increased by 23 % and 41 % at a high concentration of ethanol at pH 8.9, suggesting the stabilization role of graphene in enzyme loading. The study provides us a deep analysis on structures and performances of the bioanode incl. electrochemistry, X-ray photoelectron spectra, and atomic force microscopy images, which is significant to develop the new methods to construct 3D porous electrodes in energy conversion device. 相似文献
14.
氢能的引入能有效提升配电网的供电可靠性,而电解水制氢是实现低碳转型的关键技术,开发高效的电解水催化剂势在必行。过渡金属氧化物储量大、催化活性高,是具有广阔应用前景的析氧反应催化剂。本文通过射频等离子体处理制备石墨烯上负载Co3O4析氧催化剂,XRD、Raman和XPS测试结果显示,二维结构石墨烯的引入加速表面电子迁移,增大了反应面积。等离子体处理促进了纳米粒子在石墨烯上的负载,利用等离子体刻蚀作用在催化剂表面制造出大量碳结构缺陷和氧空位结构,改善了活性位点分布,有效调控Co3O4电子结构,提高析氧催化活性。电化学测试表明,本文中合成的Co3O4@rGO在电流密度为50 mA·cm-2时的过电位为410 mV,动力学反应速率较快,表现出优于商业IrO2的析氧催化活性。 相似文献
15.
Patrick Imrie Jianyong Jin 《Journal of polymer science. Part A, Polymer chemistry》2022,60(2):149-174
4D printing is an exciting branch of additive manufacturing. It relies on established 3D printing techniques to fabricate objects in much the same way. However, structures which fall into the 4D printed category have the ability to change with time, hence the “extra dimension.” The common perception of 4D printed objects is that of macroscopic single-material structures limited to point-to-point shape change only, in response to either heat or water. However, in the area of polymer 4D printing, recent advancements challenge this understanding. A host of new polymeric materials have been designed which display a variety of wonderful effects brought about by unconventional stimuli, and advanced additive manufacturing techniques have been developed to accommodate them. As a result, the horizons of polymer 4D printing have been broadened beyond what was initially thought possible. In this review, we showcase the many studies which evolve the very definition of polymer 4D printing, and reveal emerging areas of research integral to its advancement. 相似文献
16.
17.
《Mendeleev Communications》2022,32(4):523-526
Five new dyes with D–π–A structure bearing 5-(methylene)-rhodanine-3-acetic acid as an acceptor-anchoring part and thieno[3,2-b]indole or benzo[g]thieno[3,2-b]indole as an electron-donating part were synthesized and applied as photosensitizers for dye-sensitized solar cells (DSSCs). In addition, thermal stability, optical and electrochemical properties of these dyes were investigated. The highest PCE value of 1.09% (Jsc = 3.01 mA cm–2, Voc = 0.53 V, FF = 0.69) was achieved for DSSC based on benzo[g]thieno[3,2-b]indole dye under AM 1.5G irradiation. 相似文献
18.
19.
Rose Morris-Wright 《Journal of Pure and Applied Algebra》2021,225(1):106468
Parabolic subgroups are the building blocks of Artin groups. This paper extends previous results of Cumplido, Gebhardt, Gonzales-Meneses and Wiest, known only for parabolic subgroups of finite type Artin groups, to parabolic subgroups of FC-type Artin groups. We show that the class of finite type parabolic subgroups is closed under intersection. We also study an analog of the curve complex for mapping class group constructed by Cumplido et al. using parabolic subgroups. We extend the construction of this complex, called the complex of parabolic subgroups, to FC-type Artin groups. We show that this simplicial complex is, in most cases, infinite diameter and conjecture that it is δ-hyperbolic. 相似文献
20.